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Soil Chemistry

12 min read

How soil forms and what it contains

Soil forms when weathering breaks rock into small particles and organisms add humus (decayed organic matter). Soil is a mixture of mineral particles (sand, silt and clay), organic matter, water, air and living organisms. A soil profile shows layers called horizons.

A soil profileA vertical slice through soil showing layers called horizons. The top is the O horizon of dead plant matter. Below it is the dark A horizon or topsoil rich in humus, then the B horizon or subsoil with clay washed down from above, then the C horizon of broken rock, and finally solid bedrock.O horizondead leaves and humusA horizon (topsoil)dark, rich in humus; roots and organismsB horizon (subsoil)clay and minerals washed downC horizonbroken rockBedrocksolid rockdepth
ParticleSizeProperties
Sand0.05–2 mmLarge gaps: drains quickly, holds little water or nutrients
Silt0.002–0.05 mmMedium
ClayLess than 0.002 mmHolds water and nutrients, but drains slowly and may become waterlogged

Soil pH and nutrient availability

Most crops grow best between pH 6 and 7. In acid soil (pH below 5.5) aluminium and manganese become soluble and toxic and phosphorus is locked up; in alkaline soil iron and some trace elements become unavailable. Soils become acidic through rain, leaching, and the use of ammonium fertilisers. Liming (adding calcium carbonate or calcium hydroxide) raises the pH: CaCO₃ + 2H⁺ → Ca²⁺ + H₂O + CO₂.

Cation exchange capacity and soil nutrients

Clay and humus have negative surfaces that hold positive ions (Ca²⁺, Mg²⁺, K⁺, NH₄⁺) and exchange them with the soil water. The cation exchange capacity (CEC) measures how many cations a soil can hold. A soil with a high CEC (clay, humus) keeps nutrients better against leaching than sandy soil.

NutrientNeeded forSign of deficiencySource
Nitrogen (N)Leaves and proteinPale yellow older leaves, stunted growthUrea, ammonium nitrate, manure, legumes
Phosphorus (P)Roots, flowers, seedsPurple leaves, poor rootsSuperphosphate, bone meal
Potassium (K)Water balance, fruitsBrown leaf edgesPotassium chloride, wood ash
Calcium (Ca)Cell wallsBlossom-end rot in tomatoesLime, gypsum
Magnesium (Mg)ChlorophyllYellow between the veinsDolomite
Try itNutrients in a bag of NPK fertiliser

An NPK fertiliser is labelled with the percentages of nitrogen (N), phosphorus pentoxide (P₂O₅) and potassium oxide (K₂O). Choose the bag mass and the label.

Managing soil

PracticeEffect
Adding compost and manureRaises humus, CEC and water retention
Crop rotation with legumesBacteria in the roots fix nitrogen
LimingRaises pH
Mulching and terracingReduces erosion and keeps moisture
Avoiding over-fertilisingPrevents nitrate pollution of water and soil acidification
Soil forms slowly over hundreds of years.
Check yourself Which soil has the greatest water-holding capacity?
Check yourself Which treatment raises the pH of acid soil?
Check yourself Yellowing between the veins of leaves suggests a shortage of…

Key terms

Humus
Dark, decayed organic matter in soil.
Cation exchange capacity
The amount of positive ions a soil can hold on its surfaces.
Liming
Adding lime to neutralise soil acidity.
Leaching
The washing of soluble nutrients down through soil by water.

Summary

  • Soil is minerals, organic matter, water, air and organisms arranged in horizons.
  • Most crops need a pH of 6 to 7; liming raises the pH.
  • Clay and humus hold cations (CEC) and reduce leaching.
  • Good soil management uses organic matter, crop rotation and careful fertiliser use.